Product ID:VOLATILE ORGANIC COMPOUNDS-GASES, M-502B
MSDS Date:07/30/1994
FSC:6630
NIIN:00N082980
MSDS Number: CGPJD

ACCUSTANDARD INC

25 SCIENCE PARK SUITE 687
NEW HAVEN, CT 06511
US

Emergency Phone: 203-786-5290

Info Phone: 203-786-5290

Cage: 0U4A8

ACCUSTANDARD INC

NEW HAVEN, CT 06513 US

Telephone: 800-442-5290

Cage: 0U4A8

METHANE, BROMO-; (BROMOMETHANE) (SARA 302/313) (CERCLA)

CAS: 74-83-9

RTECS: PA4900000

Fraction By Weight: 0.02%

OSHA PEL S,C, 20 PPM

ACGIH TLV: S, 5 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

ETHANE, CHLORO-; (CHLOROETHANE) (SARA 313) (CERCLA)

CAS: 75-00-3

RTECS: KH7525000

Fraction By Weight: 0.02%

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

ETHYLENE, CHLORO-; (VINYL CHLORIDE) (SARA 313) (CERCLA)

CAS: 75-01-4

RTECS: KU9625000

Fraction By Weight: 0.02%

OSHA PEL SEE 1910.1017

ACGIH TLV: 5 PPM, A1

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

METHANE, TRICHLOROFLUORO-; (TRICHLOROFLUOROMETHANE)

CAS: 75-69-4

RTECS: PB6125000

Fraction By Weight: 0.02%

OSHA PEL 1000 PPM

ACGIH TLV: C, 1000 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

METHANE; DICHLORODIFLUORO-; (DICHLORODIFLUOROMETHANE) (SARA

CAS: 75-71-8

RTECS: PA8200000

Fraction By Weight: 0.02%

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

METHANE, CHLORO-; (CHLOROMETHANE) (SARA 313) (CERCLA)

CAS: 74-87-3

RTECS: PA6300000

Fraction By Weight: 0.02%

OSHA PEL 100 PPM; Z-2

ACGIH TLV: S, 50 PPM/100 STEL

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

METHANOL (SARA 313) (CERCLA)

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: 99.88%

OSHA PEL S, 200 PPM

ACGIH TLV: S, 200 PPM/250 STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: TOXIC BY INGEST & INHAL. CAN BE
TOXIC BY SKIN ABSORP. AFTER INGEST/INHAL, INITIAL SYMPS MAY BE ONLY
THAT OF MILD INTOXICATION, BUT MAY BECOME SEV AFTER 12-18 HRS.
AFFECTS CNS, ESPECAILLY OPTIC NERVE. MARKED IMPAIRMENT OF VISION &
ENLARGEMENT OF LIVER HAS BEEN RPTD W/CHRONIC EXPOSURE. CHRONIC
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: EXPOS MAY ALSO CAUSE DMG TO KIDNEYS &
CNS. CAUSES DIZZ, NAUS, MUSCLE WEAK, NARCOS, RESP FAILURE. INGEST
CAN PRDCE BLNDNESS (AS LITTEL AS 30 ML) OR DEATH (AS LITTLE AS 100
ML). PRLNGD/RPTD SK IN CONT MAY CAUSE IRRIT. FETAL DEVELOPMENT
ABNORM & EFTS ON EMBRYO/FETUS HAVE BEEN RPTD FROM PRLNGD EXPOS TO
(SUPDAT)
Medical Cond Aggravated by Exposure:SKIN CONDITIONS, EYE PROBLEMS,
IMPAIRED LIVER OR KIDNEY FUNCTION.

First Aid:GET MED ASSISTANCE FOR ALL CASES OF OVEREXPOSURE. SKIN: IMMED
FLUSH THORO W/LG AMTS OF WATER. EYES: IMMED FLUSH THORO W/WATER FOR
@ LST 15 MINS. INHAL: REMOVE TO FRESH AIR; GIVE ARTF RESP IF BRTHG
HAS STOPPED. INGEST: IF CONSCIOUS, DRINK WATER & INDUCE VOMIT
IMMED AS DIRECTED BY MED PERS. NEVER GIVE ANYTHING BY MOUTH TO
UNCON PERSON. REMOVE CONTAMD CLOTHING & WASH BEFORE REUSE.

Flash Point Method:TCC
Flash Point:52.0F,11.1C
Lower Limits:6.7%
Upper Limits:36.5%
Extinguishing Media:USE WATER SPRAY, FOAM, DRY CHEMICAL, OR CO*2.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:DANGEROUS FIRE & EXPLOSIVE HAZARD. CLOSED
CONTAINERS MAY EXPLODE UPON HEATING. VAPOR CAN TRAVEL DISTANCES TO
IGNITION SOURCE AND FLASH BACK.

Spill Release Procedures:EVACUATE AREA OF ALL UNNECESSARY PERS. WEAR
SUITABLE PROT EQUIP LISTED UNDER EXPOS/PERSONAL PROT. ELIM ANY
IGNIT SOURCES UNTIL AREA IS DETERM TO BE FREE FROM EXPLO/FIRE
HAZARDS. CNTN RELEASE & ELIM IT S SOURCE, IF THIS CAN BE DONE W/OUT
RISK.(SUPDAT)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP CONTAINER CLOSED. STORE IN A COOL
AREA AWAY FROM IGNITION SOURCES AND OXIDIZERS. DO NOT BREATH VAPOR
OR MIST.
Other Precautions:DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING.
ELECTRICALLY GROUND ALL EQUIPMENT WHEN HANDLING THIS PRODUCT.

Respiratory Protection:IF WORKPLACE EXPOS LIMIT(S) OF PROD/ANY
COMPONENT IS EXCEEDED (SEE TLV/PEL), A NIOSH APPRVD AIR SUPPLIED
RESP IS ADVISED IN ABSENCE OF PROPER ENVIRONMENTAL CTL. OSHA REGS
ALSO PERMIT OTHER NIOSH APPRV D RESPS (NEGATIVE PRESS TYPE)
(SUPDAT)
Ventilation:MATERIAL SHOULD BE HANDLED OR TRANSFERRED IN AN APPROVED
FUME HOOD OR WITH ADEQUATE VENTILATION.
Protective Gloves:BUTYL RUBBER, VITON/EQUIVALENT GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER .
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. DO NOT TAKE
INTERNALLY.
Supplemental Safety and Health
EFTS OF OVEREXP: METHYL ALCOHOL IN LABORATORY TESTS INVOLVING PREGNANT
RATS. SPILL PROC: TAKE UP & CONTAINERIZE FOR PROPER DISP. COMPLY
W/FED, STATE, & LOC REGS. RESP PROT: UNDER SPECIFIED CNDTNS (SEE
SFTY EQUIP SUPPLIER). ENGINEERING &/ORADMIN CTLS SHOULD BE
IMPLEMENTED TO REDUCE EXPOSURE.

Boiling Pt:B.P. Text:149F,65C
Melt/Freeze Pt:M.P/F.P Text:-144F,-98C
Vapor Pres:97 @ 20C
Vapor Density:1.1
Spec Gravity:0.791 (H*2O=1)
Evaporation Rate & Reference:5.9 (BUAC =1)
Solubility in Water:SOLUBLE
Appearance and Odor:CLEAR LIQUID.
Percent Volatiles by Volume:99.9+

Stability Indicator/Materials to Avoid:YES
ACIDS, OXIDIZERS, REACTIVE METALS.
Stability Condition to Avoid:HEAT; CONTACT WITH IGNITION SOURCES.
Hazardous Decomposition Products:CO*X, FORMALDEHYDE.

Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL,
STATE AND LOCAL REGULATIONS .

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.